Friday, October 8, 2010

ISI Web of Knowledge Alert - Majumder M

ISI Web of Knowledge Citation Alert

Cited Article: Majumder M. Nanoscale hydrodynamics - Enhanced flow in carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
pH-Tunable Ion Selectivity in Carbon Nanotube Pores

Authors:
Fornasiero, F; Bin In, J; Kim, S; Park, HG; Wang, Y; Grigoropoulos, CP; Noy, A; Bakajin, O

Author Full Names:
Fornasiero, Francesco; Bin In, Jung; Kim, Sangil; Park, Hyung Gyu; Wang, Yinmin; Grigoropoulos, Costas P.; Noy, Aleksandr; Bakajin, Olgica

Source:
LANGMUIR 26 (18): 14848-14853 SEP 21 2010

Language:
English

Document Type:
Article

KeyWords Plus:
FILLED NANOFILTRATION MEMBRANES; NANOFLUIDIC CHANNELS; ELECTROLYTIC TRANSPORT; REVERSE-OSMOSIS; SILICON-NITRIDE; SALT REJECTION; PERMEATION; SEPARATION; SURFACE; WATER

Abstract:
The selectivity of ion transport in nanochannels is of pi Unary importance for a number of physical, chemical, and biological processes ranging from fluid separation to ion-channel-regulated cellular processes Fundamental understanding of these phenomena requires model nanochannels with well-defined and controllable structural properties Carbon nanotubes provide an ideal choice for nanofluidic studies because of their simple chemistry and structure, the atomic scale smoothness and chemical inertness of the graphitic walls, and the tunability of their diameter and length Here, we investigate the selectivity of single and, for the first time, binary salt mixtures transport through nail ow carbon nanotubes that act as the only pores in a silicon nitride membrane. We demonstrate that negatively charged carboxylic groups are responsible for the ion rejection performance of carbon nanotube pores and that ion permeation of small salts can be tuned by varying solution Investigation o
f the effect of solution composition and ion valences for binary electrolytes with common cation m a pressure-driven flow reveals that the addition of slower diffusing multivalent anions to a solution of faster diffusing monovalent anions favors permeation of the monovalent anion Larger fractions and valences of the added multivalent anions lower the rejection of the monovalent anion. In some cases, we observe negative rejection at low monovalent ion content

Reprint Address:
Bakajin, O, Porifera Inc, Hayward, CA 94545 USA.

Research Institution addresses:
[Kim, Sangil; Bakajin, Olgica] Porifera Inc, Hayward, CA 94545 USA; [Fornasiero, Francesco; Wang, Yinmin; Noy, Aleksandr] Lawrence Livermore Natl Lab, Phys & Life Sci Directorate, Livermore, CA 94550 USA; [Bin In, Jung; Grigoropoulos, Costas P.] Univ Calif Berkeley, Dept Mech Engn, Berkeley, CA 94720 USA; [Park, Hyung Gyu] ETH, Inst Energy Technol, Dept Mech & Proc Engn, Zurich, Switzerland; [Noy, Aleksandr] Univ Calif Merced, Sch Nat Sci, Merced, CA 95344 USA; [Bakajin, Olgica] Univ Calif Davis, NSF Ctr Biophoton Sci & Technol, Sacramento, CA 95817 USA

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Cited Reference Count:
67

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary

ISSN:
0743-7463

DOI:
10.1021/la101943h

IDS Number:
648JV

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